You do not have commercial license to download the 2D and 3D chemical structures in SDF files.
Structures of the first 100 compounds are demonstrated here
Please contact the Technology Transfer Office of the University of Michigan. Our representative can be contacted at:
Mr. Doug Hockstad
Sr. Technology Licensing Specialist
The University of Michigan
3003 South State Street, Suite 2071
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Fax: (734) 936-1330
dhocksta@umich.edu